AND BENZYL GROUPS and Kwo-Hrong Lai of Massachusetts, INMETRYLENECYCLGNEKADIES Amherst, Mass. 01002 (Received in USA 29 March 1971; received in UK for publication 5 April 1971) Polyhalomethyl Groups at the quaternary carbons of cross-conjugated methylenecyclohexadienes ("semibenzenes" ia) undergo fo
Migrations of Cyclopropylmethyl Groups in Thermal and Acid Catalyzed Reactions of Cyclohexadienones
β Scribed by Bernard Miller; Kwo-Hrong Lai
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 218 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Thermal migrations of ally1 groups in linearly-conjugated cyclohexadienones (e.g., eq. 1)
(1) proceed readily at temperature6 as low as [email protected]
The same reactions, as well as a disconcerting
π SIMILAR VOLUMES
Highly regioselective oxygenation products from 2,6-di-t-butylphenols display interesting chemical behavior under strongly basic conditions, being efficiently utilized for synthesis of hydroquinones, 1 o-benzoquinones, 2 cyclopentadienones, 3 3-hydroxyphenylacetic acids,' cyclopentenones, 5 and B-qu
Table 2. Selected spectroscopic data of 7a-d, 8, and 9 [a].