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Migration of the O-acetyl group in the acetonation of guaianolide rhaposerin

✍ Scribed by A. G. Berdin; V. A. Raldugin; M. M. Shakirov; A. G. Druganov; I. Yu. Bagryanskaya; Yu. V. Gatilov; A. T. Kulyyasov; S. M. Adekenov; G. A. Tolstikov


Book ID
110332955
Publisher
Springer
Year
2001
Tongue
English
Weight
264 KB
Volume
50
Category
Article
ISSN
1573-9171

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Analysis of positions of substitution of
✍ Chang Kiu Lee; Gary R. Gray πŸ“‚ Article πŸ“… 1995 πŸ› Elsevier Science 🌐 English βš– 444 KB

Described herein are methods for determining the degree of substitution (ds) and the positions of substitution of O-acetyl groups in commercial samples of partially O-acetylated cellulose. Sequential neutral methylation of the polymers, base-catalyzed ethylation, and reductive cleavage gives eight p