## Abstract The Ξ³βirradiation of bovine pancreatic ribonuclease A (RNase A) in aqueous solution were investigated at different doses by vibrational spectroscopy as well as enzymatic assay, electrophoresis, and HPLC analysis. Both functional and structural changes of the protein were caused by attac
Migration of pyrene between lipid vesicles in aqueous solution. a stopped-flow study
β Scribed by Mats Almgren
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 433 KB
- Volume
- 71
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
A fluorescence stopped-flow techmque rs described that has been used for the determination of the rate of migration of pyrene mokcules between smgle-wall lipid vesicles. The analysts of the evpenmental results suggests that the migration process occurs mainly via the aqueous phase at a rate bruited by the exrt of the pyrene molecules from the vesidw. The rate constant for the exit process was obtamed as 4 X LO* s-' at 25Β°C for pyrene in soybean !ecnhin vesicles containing 10% dicetylphosphate (vesrcle radius 320 A) m 20 mhi Trrss bufier (pIf = 7.4).
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A kinetic study has been carried out on the oxidation of N , N , N', N'-tetraethyl-p-phenylenediamine (TEPD) by metal ion like Ce4+, oxoanions viz., MnO, and CrZO:-; peroxides such as peroxomonosulphate (PMS), peroxodisulphate (PDS), and HzOz; and halogens namely Clz, Brz, and 12. The fast kinetics
In this study, the electrochemical behavior of tiron in aqueous solutions and the influence of pH were investigated. A change of pH mainly produces the following results. In acidic solutions of pH below 4, the electrode reaction of tiron exhibits a simple process at a relatively high potential with
## Abstract The kinetics of oxidation of vanillin (VAN) by diperiodatocuprate(III) (DPC) in alkaline medium at a constant ionic strength of 0.50 mol dm^β3^ was studied spectrophotometrically. The reaction between DPC and vanillin in alkaline medium exhibits 1:2 stoichiometry (vanillin: DPC). The re