Migration of polymer blend components during melt compounding
β Scribed by M. E. J. Dekkers; S. Y. Hobbs; I. Bruker; V. H. Watkins
- Publisher
- Society for Plastic Engineers
- Year
- 1990
- Tongue
- English
- Weight
- 558 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0032-3888
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β¦ Synopsis
Abstract
In this paper it is shown that a coreβshell impact modifier which is predispersed in one phase of a complex blend may migrate to another phase during melt compounding. The migration process appears to be driven by differences in the spreading behavior of the individual blend components. The details of the migration are analyzed by electron microscopy studies of partially compounded samples which were quenched, extracted, and separated from the extruder screw.
π SIMILAR VOLUMES
A very simple reduction procedure is suggested for the blend viscosities of different polymer pairs. This procedure is based on the comparison of the blend viscosity, normalized either to the matrix or to the disperse phase viscosity, with the viscosities ratio of the initial polymers (rim~rid). We
## Abstract The production of polymer blends increases at a rate of about 13 percent/y. Most of the commercial blends are multiphase systems of complex morphology, determined by the thermodynamic properties of the components and the rheology. Since the diffusion rates are relatively low, the blends