Mid- and near-infrared study of the hydrogen-bonded complexes between pentachlorophenol and proton acceptors
✍ Scribed by B. Czarniḱ-Matusewicz; Th. Zeegers-Huyskens
- Publisher
- John Wiley and Sons
- Year
- 2000
- Tongue
- English
- Weight
- 90 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0894-3230
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
The formation enthalpy, the frequency shift and integrated intensity of the '.'OH stretching vihration have heen determined for hydrogen bonded complexes formed between phenol derivatives and tetramethylthiourea or dimethylthioformamide. These data are compared with comnlexes involving carhonyl hase
Whenever hydrogen bonding is involved in molecular recognition, the possibility of a proton transfer from the donor to the acceptor arises. In most cases the pK a of the donor is far enough above the pK a of the conjugate acid of the acceptor for it to be clear that no proton transfer will occur. Ho