Microwave synthesis of vinylphosphonic acid and its derivatives
✍ Scribed by S. B. Zotov, M. O. Tuzhikov, O. I. Tuzhikov, T. V. Khokhlova
- Book ID
- 114993781
- Publisher
- SP MAIK Nauka/Interperiodica
- Year
- 2012
- Tongue
- English
- Weight
- 586 KB
- Volume
- 85
- Category
- Article
- ISSN
- 1070-4272
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## Abstract We present the synthesis and characterization of the compounds formed in a mixture of vinylphosphonic acid (VPA) and acetic anhydride used for the radical‐initiated VPA polymerization. High‐molecular‐weight PVPA with $\overline M \_{\rm w}$ up to 109 000 g · mol^−1^ was obtained from th
## Abstract **Summary:** Vinylphosphonic acid is polymerized at 80 °C by free radical polymerization to give a high‐molecular‐weight polymer ($\overline M \_{\rm w}$ of 6.2 × 10^4^) as determined by static light scattering. High‐resolution NMR spectroscopy is used to gain microstructure information