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Microwave stark spectroscopy of continuous supersonic molecular beams: OCS in pure and in Ar- and He-seeded beams

✍ Scribed by H.S. Zivi; A. Bauder; Hs.H. Günthard


Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
356 KB
Volume
83
Category
Article
ISSN
0009-2614

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✦ Synopsis


A broad-band mIcrowave spectrometer has been constructed usmg a groove gurde Stark cell through whtch a suprrsoruc moIecufar beam is dlrecred parallel to the mlcrowave radmtron The J= 1 4 0 rotational tranntron of OCS ui pure and seeded beams has been observed m em-on with bnewldths from 1.1 to 2 kHz (hwhm) Our technique offers a converttent too: for molecular beam dtagnostin


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The ti = 0, I-doubler transitions in the fat excited state of the bending vibration of 16012~3% have been investigated using the molecular-beam electric-resonance method. The I-doubling constant up to second order in JU+lI has beea derived. The electric and magnetic properties obtained are the elect