Microwave Spectrum of the C3S Molecule in the Vibrationally Excited States of Bending Modes, v4 and v5
β Scribed by J.A. Tang; S. Saito
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 679 KB
- Volume
- 169
- Category
- Article
- ISSN
- 0022-2852
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β¦ Synopsis
Rotational spectra of the linear (\mathrm{C}{3} \mathrm{~S}) molecule in the excited bending vibrational states (v{5}=1), 2.3, and 4 (CCS bending) and (v_{4}=1) (CCC bending) have been observed in the frequency range (116-383 \mathrm{GHz}) with a source-modulated microwave spectrometer. Molecular constants of vibrationrotation interaction terms up to higher orders were determined by the least-squares fitting of about 460 transition frequencies. The determined (\alpha_{t}, q_{t}), and (q_{1}^{J}) constants showed a good coincidence with those of ab initio calculation. The sign and magnitude of (\gamma_{l l}), the dependence of the rotational constant (B_{\mathrm{v}}) on vibrational angular momentum, was explained by a symmetric-top-like molecular model. The constant (q_{t}^{K}), the dependence of the (l)-type doubling and resonance constant (q_{t}) on vibrational angular momentum, was determined experimentally for the first time. The obtained value of (q_{i}^{K}) was a thousand times greater than the theoretical estimate given by Watson's expression, but the order of magnitude of the experimental value can be understood by an analogy with a slightly asymmetric-top molecule. (1995 Academic Press. Inc.
π SIMILAR VOLUMES
The vibration-rotation spectrum of 13 C 2 D 2 has been recorded in the infrared region between 420 and 1100 cm -1 with an effective resolution ranging from 0.004 to 0.006 cm -1 , and in the millimeter-wave region between 68 and 518 GHz. A total of about 1400 rovibrational transitions (66 of which ha