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Microwave spectrum of FeCl radical in the electronic ground 6Δi state

✍ Scribed by Mitsutoshi Tanimoto; Shuji Saito; Toshiaki Okabayashi

Book ID
103035427
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
273 KB
Volume
242
Category
Article
ISSN
0009-2614

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✦ Synopsis

The rotational spectrum of the FeC1 radical in the electronic ground state was observed by using a source-modulated millimeter-wave spectrometer. This species was produced in a free-space cell by glow-discharging a mixture of helium and aluminum trichloride vapor. Iron atoms were extracted during the discharge from the stainless-steel electrodes in the cell. The spectrum was observed for the two lowest-lying spin components of the inverted sextet A state. The rotational and centrifugal distortion constants were determined by a least-squares fit to the line frequencies of each spin substate.

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Microwave Spectrum of the PD2Radical in
Microwave Spectrum of the PD2Radical in the2B1Ground Electronic State
✍ Tsuyoshi Hirao; Shin-ichi Hayakashi; Satoshi Yamamoto; Shuji Saito 📂 Article 📅 1998 🏛 Elsevier Science 🌐 English ⚖ 317 KB

The rotational spectrum of the PD 2 radical in the 2 B 1 ground electronic state was observed in the region 165-463 GHz using a source-modulated microwave spectrometer. The PD 2 radical was generated in a free-space absorption cell by a dc glow discharge of D 2 over red phosphorus grains which were