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Microwave Spectrum of 2,6-Difluorobenzonitrile

✍ Scribed by S.D. Sharma; S. Doraiswamy

Publisher: Elsevier Science
Year: 1996
Tongue: English
Weight: 204 KB
Volume: 180
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1996.0219

No coin nor oath required. For personal study only.

✦ Synopsis

The molecule 2,6-difluorobenzonitrile has been analyzed in the frequency ranges from 8 to 12 GHz and from 31 to 40 GHz at dry ice temperature using a conventional 100 kHz and a Hewlett-Packard 33 kHz Stark-modulated microwave spectrometer, respectively. The rotational and centrifugal distortion constants (in MHz) are A ˜Å 1761.032 (43), B ˜Å 1501.359 (18), C ˜Å 810.524 ( 18), D J Å 00.00691 (6), D JK Å 00.03236 (12), D K Å 0.11642 (64), d J Å 00.003470 (3), and d K Å 00.028937 (16). The benzene ring appears to be distorted if the generally accepted bond lengths of the peripheral bonds are used.

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