๐”– Bobbio Scriptorium
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Microwave spectrum, dipole moment and molecular structure of 1,2-dithiete

โœ Scribed by M. Rodler; A. Bauder

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
381 KB
Volume
114
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

I ,2-&hiete has been produced by very-low-pressure pyrolysis of 1,3_bithioIe-2-one. Its microwave spectrum has been observed and amed over the range X8-27 GIiz. All rotational constants and three centnfugal distortion constants have been adjusted in a least-squares fit from 12 rotational transitions in the vibrational ground state. The permanent electnc &pole moment 4 = 1329(2) D has been determined from Stark sphttings and the symmetry Czv has been established. A molecular structure is proposed which is compatible with the measured rotational constants and with ab mitio calculations.

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Microwave spectrum, dipole moment and st
Microwave spectrum, dipole moment and structure of 1,1-difluorocyclohexane
โœ D. Damiani; L. Ferretti ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 362 KB

From the analysis of the miaowave rotationa spectrum of IJdifluorocyclohexane in the frequency region 8-40 GHz the rotational constants (.4 = 3191.781, B = 1759.768, C= 1512.293 nlHzj, the centrifugal distortion coefficients @J= 124 X 104,DJ~--2.92 X 104, 0~ = -8.20 X 10d3) and the dipole moment and