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Microwave spectroscopic detection of BFHOH and BH(OH)2

✍ Scribed by Yoshiyuki Kawashima; Harutoshi Takeo; Chi Matsumura

Book ID
103019485
Publisher
Elsevier Science
Year
1978
Tongue
English
Weight
240 KB
Volume
57
Category
Article
ISSN
0009-2614

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✦ Synopsis

Transient molecules, BFHOH and BH(OH)z, have been detected by microwave spectroscopy in the hydrolyses of diborane and BF3. Their conformations have been determined from the inertia defects and the differences in moments of inertia between normal and deuterated species.

πŸ“œ SIMILAR VOLUMES

Microwave Spectroscopic Detection of Flu
Microwave Spectroscopic Detection of Fluoroborane, BH2F
✍ H. Takeo; M. Sugie; C. Matsumura πŸ“‚ Article πŸ“… 1993 πŸ› Elsevier Science 🌐 English βš– 309 KB

Fluoroborane, \(\mathrm{BH}_{2} \mathrm{~F}\), has been detected as a transient chemical species in the reaction of diborane with trifluoroborane by microwave spectroscopic technique. The rotational constants obtained for three isotopic species of this molecule are (in \(\mathrm{MHz}\) ):