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Microwave-promoted, one-pot conversion of alkoxymethylated protected alcohols into their corresponding nitriles, bromides, and iodides using [bmim][InCl4] as a green catalyst

✍ Scribed by Arsalan Mirjafari; Iraj Mohammadpoor-Baltork; Majid Moghadam; Shahram Tangestaninejad; Valiollah Mirkhani; Ahmad Reza Khosropour

Publisher: Elsevier Science
Year: 2010
Tongue: French
Weight: 224 KB
Volume: 51
Category: Article
ISSN: 0040-4039
DOI: 10.1016/j.tetlet.2010.04.056

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✦ Synopsis

The Lewis acid room temperature ionic liquid, [bmim][InCl 4 ], was found to be an efficient and green catalyst for the highly chemoselective and one-pot conversion of MOM-or EOM-ethers into their corresponding nitriles, bromides, and iodides under microwave irradiation. The procedures are simple, rapid, and high yielding. The catalyst exhibited a remarkable reactivity and is reusable.

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ChemInform Abstract: Microwave-Promoted,

ChemInform Abstract: Microwave-Promoted, One-Pot Conversion of Alkoxymethylated Protected Alcohols into Their Corresponding Nitriles, Bromides, and Iodides Using [bmim][InCl4] as a Green Catalyst.

✍ Arsalan Mirjafari; Iraj Mohammadpoor-Baltork; Majid Moghadam; Shahram Tangestani 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB

## Abstract Direct transformation of benzylic and aliphatic Mom and Eom ethers is achieved with the corresponding tetrabutylammonium salts.