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Microwave Measurements of the Spectra and Molecular Structure for the Monoenolic Tautomer of 1,2- Cyclohexanedione

✍ Scribed by Pejlovas, Aaron M.; Barfield, Michael; Kukolich, Stephen G.


Book ID
125531844
Publisher
American Chemical Society
Year
2014
Tongue
English
Weight
577 KB
Volume
119
Category
Article
ISSN
1089-5639

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The molecular structure of 1,2 cyclohexanedione has been investigated in the vapor at 295 K. The electron diffraction data were consistent with a model of pure enol form (2-hydroxy-2-cyclohexen-1-one) with the six-membered ring in the sofa conformation (with C 5 out of the plane formed by the other

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A pulsed-beam Fourier transform microwave spectrometer was used to investigate the rotational spectrum of 1,2dithia-3,5-cyclohexadiene in the range 8 to 18 GHz. The observed a-type transitions were fit to a Watson asymmetric top Hamiltonian, giving the following rotational constants for the normal i