Microwave measurements of bromine quadrupole coupling constants and the molecular structure of XeHBr
โ Scribed by S.G. Kukolich; E.J. Campbell
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 302 KB
- Volume
- 94
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
Mxrowa~c rotational spectra for various isotopic forms of the XeHBt comple\ were obtained using a pulsed-nozzle, Fourier transform spectrometer. The molecular constmts tepq). Bo and Di v. ere obtained from J = 6 -7, 7 -8 and 8 -9 tr.msitions The xenon-bromine separation distance isrXe_Br = 4.419 A. From DJ J stretching force constant k, = 0.0 18 mdyne/A and vv cll depth E = 244 cm-r xv em obtained
๐ SIMILAR VOLUMES
The microwave spectrum of bromodifluoromethane, CHBrF2 (Halon 1201) has been studied for the first time from 7 to 40 GHz. A least-squares analysis of the observed c-type transition frequencies gave rotational and centrifugal distortion constants and components of the bromine nuclear quadrupole coupl