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Microwave irradiation as an energy source in poly(ethylene terephthalate) solvolysis

✍ Scribed by Andrej Kržan


Book ID
101255914
Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
105 KB
Volume
69
Category
Article
ISSN
0021-8995

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✦ Synopsis


Solvolysis by glycols and alcohols is an established method for the chemical recycling of poly(ethylene terephthalate) (PET). In our work, we investigated the use of microwave radiation as the energy source in PET solvolysis reactions, and the conditions that govern its effectiveness. The main advantage of microwave use are short reaction times, between 4 and 10 min, in which complete PET degradation is achieved. Solvolysis reagents used were methanol, propylene glycol, and polyethylene glycol 400.


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## Abstract This article covers the depolymerization of poly(ethylene terephthalate) (PET) under microwave irradiation in neutral water. The reaction was carried out in a sealed reaction vessel in which the pressure (or temperature) was controlled. The hydrolytic product contained terephthalic acid