✦ LIBER ✦

Microwave electronic spectra of the Ar2+ and Ne2+ ions: a combined neutral/ion molecular beam technique

✍ Scribed by Alan Carrington; Andrew M. Shaw; Susie M. Taylor

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 522 KB
Volume: 241
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(95)00644-j

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✦ Synopsis

We describe a new ion source in which a nozzle beam of neutral molecules is ionised by an electron beam and the resulting molecular ion beam is studied by microwave spectroscopic methods. This ionisation technique results in significant population of the near-dissociation levels of the molecular ion, so that a sensitive state-selective electric field dissociation method can be used to detect the spectra. We have observed the first state-to-state resonant electronic spectra of the Ar~-and Ne~-ions.

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