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Microwave-Assisted Synthesis of Pyrazoles by 1,3-Dipolar Cycloaddition of Diazo Compounds to Acetylene Derivatives.

✍ Scribed by Irena Zrinski; Marina Juribasic; Mirjana Eckert-Maksic

Publisher
John Wiley and Sons
Year
2007
Weight
27 KB
Volume
38
Category
Article
ISSN
0931-7597

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Convenient Room-Temperature, Mercury-Assisted Synthesis of Tetrazoles by 1,3-Dipolar Cycloaddition
✍ Thomas M. KlapΓΆtke; Burkhard Krumm; Richard Moll πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons 🌐 English βš– 373 KB πŸ‘ 1 views

## Abstract The intermolecular 1,3‐dipolar cycloaddition of organomercury(II) azides R^1^HgN~3~ (R^1^ = Me, Ph) to organonitriles R^2^CN (R^2^ = Me, Ph, C~6~F~5~) forms organomercury(II) tetrazoles R^1^Hg(N~4~C)R^2^ [R^1^ = Me, R^2^ = Me (1); R^1^ = Me, R^2^ = Ph (2); R^1^ = Ph, R^2^ = Me (3); R^1^