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Microwave-Assisted Synthesis and Bioactivity of Novel 2,2,4,5-Tetrasubstituted 3-Dichloroacetyl-1,3-oxazolidines

✍ Scribed by Ye, Fei; Yang, Lei; Fu, Ying; Gao, Shuang

Book ID
118276589
Publisher
Japan Institute of Heterocyclic Chemistry
Year
2011
Tongue
English
Weight
670 KB
Volume
83
Category
Article
ISSN
0385-5414

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Regio- and stereoselective microwave-assisted synthesis of 5-alkyl-4-alkenyl-4-phenyl-1,3-oxazolidin-2-ones
✍ Marta Amador; Xavier Ariza; JΓ©rΓ©mie Boyer; Lucia D’Andrea; Jordi Garcia; Jaume G πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 French βš– 588 KB

Quaternary a-amino acids a b s t r a c t Chiral symmetrical alk-2-yne-1,4-diols have been stereoselectively transformed into 5-alkyl-4-alkenyl-4phenyl-1,3-oxazolidin-2-ones, which are precursors of quaternary a-amino b-hydroxy acids. The key step was the cyclization of the bis(tosylcarbamates) of 2-