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Microwave-Assisted Preparation of N -Alkylated Saccharins and Their Reactions with Potassium t-Butoxide

✍ Scribed by Jakopin, Žiga; Dolenc, Marija Sollner

Book ID
118020140
Publisher
Taylor and Francis Group
Year
2010
Tongue
English
Weight
332 KB
Volume
40
Category
Article
ISSN
0039-7911

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N-nitrosohydroxylamines I. Acetolysis an
N-nitrosohydroxylamines I. Acetolysis and acid-catalyzed hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines. Reaction with potassium t-butoxide
✍ Kunio Kano; Jean-Pierre Anselme 📂 Article 📅 1992 🏛 Elsevier Science 🌐 French ⚖ 1004 KB

The major products of the hydrolysis of N,O-dibenzyl-N-nitrosohydroxylamines (3) are the denitrosated parent hydroxylamines (6); under mom forcing conditions, products of the further hydrolysis of 6 are obtained. Acetolysis in acetic acid gives the benzyl acetates derived from both N-and 0-substitue