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Microwave and Millimeter-Wave Spectra of 13CD3OH

✍ Scribed by I. Mukhopadhyay; K.V.L.N. Sastry; R.M. Lees; M. Winnewisser

Publisher: Elsevier Science
Year: 1995
Tongue: English
Weight: 372 KB
Volume: 172
Category: Article
ISSN: 0022-2852
DOI: 10.1006/jmsp.1995.1159

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✦ Synopsis

The microwave and millimeter-wave absorption spectra of ({ }^{13} \mathrm{C})-substituted (\mathrm{CD}{3} \mathrm{OH}) have been investigated in the frequency range (18-116 \mathrm{GHz}). All transition frequencies have been measured for the (J=1 \leftarrow 0) to (J=3 \leftarrow 2 a)-type (R)-branch multiplets for the lowest three torsional states. Asymmetry splittings were observed for the (K=1) and 2 lines of the (A) torsional symmetry species. In addition, frequencies have been measured for a substantial number of (b)-type transitions in the torsional ground state. including the (K=1 \leftarrow 0 E{1}, K=1 \leftarrow 2 E_{1}), and (K=3 \leftarrow 2 A Q) branches. The measured frequencies of the a-type transitions have been fitted to a semiempirical torsionrotation Hamiltonian and accurate a-type spectroscopic parameters have been determined. C) 1995 Academic Press, Inc.

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