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Microwave Accelerated Polymerization of 2-Phenyl-2-oxazoline: Microwave or Temperature Effects?

✍ Scribed by Richard Hoogenboom; Mark A. M. Leenen; Frank Wiesbrock; Ulrich S. Schubert

Publisher
John Wiley and Sons
Year
2005
Tongue
English
Weight
203 KB
Volume
26
Category
Article
ISSN
1022-1336

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✦ Synopsis

Abstract

Summary: Investigations regarding the cationic ring‐opening polymerization of 2‐phenyl‐2‐oxazoline under microwave irradiation and conventional heating are reported. This study was inspired by contradictory reports of the (non‐)existence of non‐thermal microwave effects that might accelerate the cationic ring‐opening of 2‐oxazolines. The polymerization of 2‐phenyl‐2‐oxazoline was investigated under pressure in acetonitrile and under reflux (or at the boiling point of butyronitrile in a closed vessel) in butyronitrile utilizing a single‐mode microwave reactor and automated synthesis robots with conventional heating.
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