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Microstructure of copolymers of methyl methacrylate with ethyl methacrylate

✍ Scribed by A.S. Brar; G.S. Kapur; S.K. Dubey


Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
124 KB
Volume
24
Category
Article
ISSN
0014-3057

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✦ Synopsis


The reactivity ratios for the copolymerization of methyl and ethyl methacrylates were calculated by the method of Kelen and Tudos. The triad sequence distributions were then determined by means of a computer program due to Harwood. The calculated distributions agree well with those found by 13C-IH-NMR spectroscopy.


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Poly(ethyl a-benzoyloxymethylacrylate) (EBMA) and copolymers of methyl methacrylate (MMA) with EBMA have been prepared by free radical polymerization. Monomer precursors of ethyl a-benzoyloxymethylacrylate have likewise been polymerized. Glass transition temperatures (T g ) of homo and copolymers ha