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Microscopic solvent shifts in the electronic spectra of large van der waals molecules

✍ Scribed by Samuel Leutwyler

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 508 KB
Volume: 107
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(84)85130-1

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✦ Synopsis

The experimental red-shifts of the electronic origins of a number of law non-polar \nan der Waals molecules are reported. A comparison with the theoretical red-shifts calculated by 3 form&m given by Lonpuet-H&ins and Poplc yields a good correlation, reflecting the dominant role of dispersion interactions in these compleses.

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