Microscopic and macroscopic solvation of aromatic molecules in aliphatic hydrocarbons
β Scribed by Narda Ben-Horin; Uzi Even; Joshua Jortner
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 681 KB
- Volume
- 177
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The Se+& transltion of heteroclusters of anthracene and tetracene with alkanes was interrogated by resonant two-colour twophoton ionization. The microscopic spectral shifts of tetracene,heptane, (n= l-12) clusters converge for n> 7 to those of the tetracene-heptane solution spectra, documenting a spectroscopic manifestation of the gradual "transition" from finite to infinite
π SIMILAR VOLUMES
The reactions of various substrates including aliphatic hydrocarbons, aromatic compounds, and olefins were investigated in subcritical carbon tetrachloride. Ketones and sulfones were stable under the employed conditions. The coupling adducts between olefins and carbon tetrachloride were obtained fro