Microkinetics of methane oxidative coupling
โ Scribed by Jianjun Sun; Joris W. Thybaut; Guy B. Marin
- Publisher
- Elsevier Science
- Year
- 2008
- Tongue
- English
- Weight
- 907 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0920-5861
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The reaction mechanism of the oxidative coupling of methane (OCM) has attracted world wide attention. In this paper a series of catalysts modified by Li +, Na รท containing superionic conductors or solid electrolytes have been tested for the OCM. It was observed that the addition of A2BO4 (A: Li รท, N
A heterogeneous kinetic scheme, describing the catalyst surface reactions involved in the oxidative coupling of methane, is connected to detailed homogeneous kinetic scheme with the aim of simulating the reacting behaviour of mixtures of oxygen and light hydrocarbons. The homogeneous part of the sch