Microelectrode studies of the Zn/Zn(II) and Fe(II)/Fe(III) couples in low molecular weight oligomeric electrolytes

Possible role of Lewis acid catalysis in

Possible role of Lewis acid catalysis in the oxidation of alkenes and α,β-unsaturated ketones using bleomycin-zn(ii) and bleomycin-fe(iii)-iodosylbenzene in aqueous methanol

✍ Robert M. Moriarty; Raju Penmasta; Indra Prakash 📂 Article 📅 1985 🏛 Elsevier Science 🌐 French ⚖ 255 KB

CeH510 in CH30H-HZ0 is activated towards electrophilic attack upon various alkenes by Fe(C104)'9H20, Fe(II1) bleomycin and Zn(I1) bleomycin. The results imply that direct transfer of oxygen from an Fe(V)=0 intermediate is not required in the mechanism of oxygenation by iron-containing species, and t