MICROBIOLOGICAL OXYGENATION OF STEROIDS AT CARBON 11
β Scribed by Peterson, D. H.; Murray, H. C.
- Book ID
- 120620767
- Publisher
- American Chemical Society
- Year
- 1952
- Tongue
- English
- Weight
- 241 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
We wish to report various novel reactions and intermediates which permit the development of efficient total syntheses of a wide variety of 11-oxygenated steroids from intermediates which have previously been converted to estrone, 1,2 equilenin, 1,2 equilin,3 and other steroid hormones.
## Abbrc-3,3-Ethy~ory-~~drostme-l7_onc and utronc 3-methyl ether were subjected to cIJ&er~ coodauatio~~ with ethyl acetate and aifluoroacan~c. 7-h~ a101 aatatea of lCtri!?uoroaceyl duintiva undawnt hydrogxolysis with the formation of trithorocthyl CO~~~UII&. ## UV and 1R spaxrd data and other c