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Microbial reduction of cyclohexanones

✍ Scribed by Roseli Maria De Conti; André L.M. Porto; J. Augusto; R. Rodrigues; Paulo J.S. Moran; Gilson P. Manfio; Anita J. Marsaioli

Book ID
114395484
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
75 KB
Volume
11
Category
Article
ISSN
1381-1177

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📜 SIMILAR VOLUMES

Synthesis and reduction of chiral sulfin
Synthesis and reduction of chiral sulfinyl cyclohexanones
✍ M.C. Carreño; J.L.García Ruano; A. Rubio 📂 Article 📅 1987 🏛 Elsevier Science 🌐 French ⚖ 264 KB

The reaction of cyclohexanone with (S)-(-)-menthyl-p-toluenesulfinate in the presence of Pr@gBr yields a mixture of enantiomerically pure 2-p-tolylsulfinylcyclohexanone diastereoisomers. Their stereoselective reduction to chiral hydroxysulfoxides is also reported. The important role of chiral 8-ket