Microbial hydroxylation and functionalization of synthetic bicyclic enones
β Scribed by A. Hammoumi; G. Revial; J. D'Angelo; J.P. Girault; R. Azerad
- Book ID
- 104214861
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- French
- Weight
- 361 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The reglo-and stereoselective hydroxylation of substituted octalones by various fungal strams has been evaluated. Several hydroxylated derivatives have been obtained and the potential of this method for the preparation of useful cblral synthons is discussed.
π SIMILAR VOLUMES
heptanes have been synthesized in a short route. These compounds containing benzamide or benzenesulfonamide groups are good substrates for microbial oxidation of unactivated carbons by B. bassiana.
Sct,7[3,9ct, 1013,13ct-Pentaacetoxy-4(20) . l 1-taxadiene I was selectively transformed into its l[3,14[3-hydroxylated derivatives 2, 3, and 1 l(15~.l)abeotaxane 4 by different filamentous fungi. Microbial transformation of a series of taxoids with a 4(20) exocyclic double bond was described. The m