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Microbial asymmetric oxygenation of an organometallic sulfide

✍ Scribed by Yoshimitsu Yamazaki; Kuniaki Hosono

Publisher
Springer Netherlands
Year
1989
Tongue
English
Weight
132 KB
Volume
11
Category
Article
ISSN
0141-5492

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πŸ“œ SIMILAR VOLUMES

An efficient asymmetric oxidation of sul
An efficient asymmetric oxidation of sulfides to sulfoxides
✍ Philippe Pitchen; Henri B. Kagan πŸ“‚ Article πŸ“… 1984 πŸ› Elsevier Science 🌐 French βš– 240 KB

The Sharpless reagent (Ti(OiPr)4 t 1 mol eq. diethyl tartrate (DET) t 2 J-BuOOH) modified by addition of one mol eq. H20 gives a new homogeneous reagent which cleanly oxidizes sulfidesinto sulfoxides in dichloromethane. The best results were obtained for the stoichiometry Ti/DET/ H20/J-BuOOH = 1:2:1