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Micro-Ice-Lens Formation in Porous Solid

โœ Scribed by Max J. Setzer


Book ID
102582404
Publisher
Elsevier Science
Year
2001
Tongue
English
Weight
327 KB
Volume
243
Category
Article
ISSN
0021-9797

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โœฆ Synopsis


The micro-ice-lens model is outlined. It is based on the stability criteria for the triple-phase condition of unfrozen water, ice, and vapor in porous solids far below the bulk freezing point as described in Ref. (1). Due to these stability criteria a negative pressure is generated in the unfrozen gel-water, increasing with falling temperature. The temperature change acts like a piston, squeezing water out of the not infinitely rigid gel-matrix during cooling: frost shrinkage. The water is trapped at the macroscopically behaving micro-icelenses. They act as a valve since they hinder the trapped water from flowing back to the expanding gel during heating. If external water is available it is sucked in. A cyclic freeze thaw attack works like a pump-called therefore the micro-ice-lens pump-increasing the degree of saturation with every cycle far above isothermal saturation level. Only if a critical degree of saturation is reached by this pumping does damage set in due to the expansion of ice. The model is supported by the results of frost testing, like the CDF/CIF test. Frost-heaving phenomena are based on the same triple-phase conditions and transport.


๐Ÿ“œ SIMILAR VOLUMES


Melting of ice in porous solids
โœ Rennie, George K.; Clifford, John ๐Ÿ“‚ Article ๐Ÿ“… 1977 ๐Ÿ› The Royal Society of Chemistry โš– 757 KB
Freezing processes in porous media: Form
โœ F Talamucci ๐Ÿ“‚ Article ๐Ÿ“… 2003 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 717 KB

moist porous soil is freezing, a volume expansion is generally observed. The volume increase is mainly due to a water migration process from the base of the soil up to the freezing front, which separates the lower unfrozen part from the upper frozen one. The coupled heat-mass transfer process is acc