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Michael additions to acrylonitrile, methyl acrylate and methyl vinyl ketone to Nb-benzylidenetryptophan methyl ester

✍ Scribed by Miguel F. Braña; Mercedes Garrido; María L. López Rodríguez; M. José Morcillo

Book ID
112129526
Publisher
Journal of Heterocyclic Chemistry
Year
1990
Tongue
English
Weight
107 KB
Volume
27
Category
Article
ISSN
0022-152X

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📜 SIMILAR VOLUMES

A stepwise mechanism for the uncatalyzed
A stepwise mechanism for the uncatalyzed michael addition of acetylacetone to methyl vinyl ketone
✍ Sanjib Deuri; Prodeep Phukan 📂 Article 📅 2011 🏛 John Wiley and Sons 🌐 English ⚖ 252 KB

## Abstract A stepwise mechanism for the uncatalyzed Michael addition of acetylacetone (AcAc) to methyl vinyl ketone (MVK) has been studied by ab initio calculations at the MP2/6‐31+G (d, p)// B3LYP/6‐31+G (d, p) level of theory. This stepwise mechanism is initiated by a Diels–Alder‐type attack of