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Michael Additions of Nitroform. II. The Nitrite Elimination Reaction 1

โœ Scribed by Kamlet, Mortimer J.; Kaplan, Lloyd A.

Book ID
121000948
Publisher
American Chemical Society
Year
1963
Tongue
English
Weight
589 KB
Volume
28
Category
Article
ISSN
0022-3263

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โœ Graham Maw; Carl Thirsk; Andrew Whiting ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 109 KB

A series of (E)-ammonium or amino acrylates have been prepared via the Michael addition of methyl (Z)-iodoacrylate and several secondary and tertiary alkylamines. Tertiary amines undergo concomitant addition-dealkylation, almost quantitatively producing (E)-dialkylamino acrylates.