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Michael addition of nitroalkanes to dimethyl maleate with DBU. A new direct method for the synthesis of polyfunctionalized α,β-unsaturated esters

✍ Scribed by Roberto Ballini; Alessandro Rinaldi


Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
257 KB
Volume
35
Category
Article
ISSN
0040-4039

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## Abstract Double nucleophilic addition reactions of dialkoxy ketenesilyl acetals proceeded with α,β‐unsaturated imines to give 1,4‐ and 1,2‐double addition products, and their subsequent transformations afforded multisubstituted pyrroles in good yields. Application of this procedure to the synthe