✦ LIBER ✦

Michael addition of formaldehyde dimethylhydrazone to nitroolefins. A new formyl anion equivalent

✍ Scribed by Jose-María Lassaletta; Rosario Fernández

Book ID: 104225344
Publisher: Elsevier Science
Year: 1992
Tongue: French
Weight: 243 KB
Volume: 33
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)92538-3

No coin nor oath required. For personal study only.

✦ Synopsis

Ab#&a& Fmmklehyde dimehyihydramm mdily ndds to mrplc nitm-olefim UI the absence of baee giving P-nitrodirasthylh*e5 m very high yields. The c5mqmdbg B-nitfmidehydes can be obbkd by 07molysis.

📜 SIMILAR VOLUMES

ChemInform Abstract: Formaldehyde SAMP-H

ChemInform Abstract: Formaldehyde SAMP-Hydrazone as a Neutral Chiral Formyl Anion and Cyanide Equivalent: Asymmetric Michael Additions to Nitroalkenes.

✍ D. ENDERS; R. SYRIG; G. RAABE; R. FERNANDEZ; C. GASCH; J.-M. LASSALETTA; J.-M. L 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB

ChemInform Abstract: Asymmetric Michael

ChemInform Abstract: Asymmetric Michael Addition of Ketones to Nitroolefins Catalyzed by a New Chiral Catalyst.

✍ Lian-Jun Wang; Feng-Feng Hu 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 33 KB 👁 1 views

## Abstract A new chiral catalyst is presented for the asymmetric Michael addition of ketones to nitroolefins.

ChemInform Abstract: A New Type of Organ

ChemInform Abstract: A New Type of Organocatalyst for Highly Stereoselective Michael Addition of Ketones to Nitroolefins on Water.

✍ Siang-en Syu; Tzu-Ting Kao; Wenwei Lin 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 54 KB 👁 1 views

Methoxy(phenylthio)(trimethylsilyl)metha

Methoxy(phenylthio)(trimethylsilyl)methane as a one-carbon homologation reagent: efficient 1,4-addition of a formyl or a carboxy anion equivalent to cyclic .alpha.-enones concomitant with in situ .alpha.-alkylation

✍ Otera, Junzo; Niibo, Yoshihisa; Nozaki, Hitosi 📂 Article 📅 1989 🏛 American Chemical Society 🌐 English ⚖ 700 KB

A new synthetic equivalent of the glutam

A new synthetic equivalent of the glutamic acid γ-anion and its application to the synthesis of S-(+)-γ-carboxyglutamic acid.

✍ Michael R. Attwood; Maria G. Carr; Steven Jordan 📂 Article 📅 1990 🏛 Elsevier Science 🌐 French ⚖ 128 KB

Protected S-pyroglutamic acid can be deprotonated specifically at the y-position. The resulting enolate can be converted into y-carboxyglutamic acid in optically pure form. The naturally occurring aminoacid r\_carboxyglutamtc acid (1; Gla) is a constituent of prothrombin and other proteins.1 The nat