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Michael addition of ethyl acetoacetate to α,β-unsaturated oximes in the presence of FeCl3: a novel synthetic route to substituted nicotinic acid derivatives

✍ Scribed by Andrey M Chibiryaev; Norbert De Kimpe; Alexey V Tkachev

Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 69 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)01391-5

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✦ Synopsis

The FeCl 3 -catalyzed reaction of a,b-unsaturated oximes with ethyl acetoacetate resulted in Michael addition followed by ring closure to produce substituted nicotinic acid derivatives in a very efficient way.

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