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Michael Addition of Chiral Fischer Aminocarbene Complexes to Nitroolefins: Study on the Effect of the Michael Acceptor Structure on Diastereoselectivity

✍ Scribed by Licandro, Emanuela; Maiorana, Stefano; Capella, Laura; Manzotti, Raffaella; Papagni, Antonio; Vandoni, Barbara; Albinati, Alberto; Chuang, Shih Hsien; Hwu, Jih-Ru


Book ID
126472232
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
329 KB
Volume
20
Category
Article
ISSN
0276-7333

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The origin of virtually complete face diastereoselectivity in the organic base-catalyzed, room temperature Michael addition reactions between Ni(II)-complexes of Schiff bases of glycine and chiral 3-(Eenoyl)-4-substituted-1,3-oxazolidin-2-ones was shown to stem from the unusual mode of steric intera