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Micellar promiscuity: an expeditious approach to Morita–Baylis–Hillman reaction

✍ Scribed by Shairgojray, Bashir Ahmad; Dar, Aijaz Ahmad; Bhat, Bilal Ahmad


Book ID
120168541
Publisher
Elsevier Science
Year
2013
Tongue
French
Weight
449 KB
Volume
54
Category
Article
ISSN
0040-4039

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Acyloins from Morita–Baylis–Hillman addu
✍ Giovanni W. Amarante; Patrícia Rezende; Mayra Cavallaro; Fernando Coelho 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 137 KB

In this Letter, we describe an easy and straightforward strategy for the preparation of acyloins (a-hydroxyketones) from Morita-Baylis-Hillman adducts, based on a Curtius rearrangement. Different acyloins were obtained with good overall yield (>40% for three steps). To exemplify the synthetic useful