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Micellar, Microemulsion, and Salt Kinetic Effects upon the Reaction Fe(CN) 2 (bpy) 2 + S 2 O 82-

✍ Scribed by Sánchez, F.; Moyá, M. L.; Rodríguez, A.; Jiménez, R.; Gómez-Herrera, C.; Yánes, C.; López-Cornejo, P.

Book ID
126459270
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
185 KB
Volume
13
Category
Article
ISSN
0743-7463

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## Abstract The reaction Fe(CN)~4~(bpy)^2−^ + S~2~O~8~^2−^ has been studied in aqueous micellar solutions of __N__‐tetradecyl‐__N,N__‐dimethyl‐3‐ammonio‐1‐propanesulfonate, SB3‐14. The influence of changes in the surfactant concentration as well as in the peroxodisulfate ions concentration on __k__

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The reaction (4-CNpy ϭ 4-cyanopyridine) was studied 3Ϫ 2Ϫ Fe(CN) (4-CNpy) ϩ S O 5 2 8 in aqueous salt solutions in the presence of several electrolytes as well as in anionic, cationic, and nonionic surfactant solutions. In aqueous salt solutions the noncoulombic interactions seem to be important in

Salt effects upon reactions of different
Salt effects upon reactions of different charge type reactants: Peroxodisulphate Oxidations of Fe(CN)4(bpy)2−, cis-Fe(CN)2(bpy)2 and Fe(bpy)32+ and Iron(II) Oxidation by Co(NH3)5Cl2+
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## Abstract Salt effects on the oxidation of the iron(II) complexes Fe(CN)~4~(bpy)^2−^, __cis__‐(CN)~2~(bpy)~2~ and Fe(bpy)~3~^2+^ by S~2~O~8~^2−^ as well as on the reaction Fe^2+^ + Co(NH~3~)~5~Cl^2+^ have been studied in concentrated electrolyte solutions at 298.2 K. We have gone from anion–anion