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Micellar effect on the reduction of fluorescein dyes by photogenerated ketyl radicals

✍ Scribed by S. Lingamurthy; V. Bhanumathi; B. Sethuram; T. Navaneeth Rao


Publisher
Elsevier Science
Year
1989
Tongue
English
Weight
356 KB
Volume
42
Category
Article
ISSN
0038-092X

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Triplet quenching of 3-methyllumiflavin, thionine and thiopyronine by electron transfer from NO2 and N3 in acetonitrile, methanol and water was investigated by flash spectroscopy. The radical yield is systematically lower for N3 than for NO2, explicable by the different spin-orbit coupling propertie