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Mećhanistic dichotomy in cycloadditions to cyclooctatetraeneiron tricarbonyl. X-ray crystal structure analysis of the TCNE and CSI adducts

✍ Scribed by L.A. Paquette; S.V. Ley; M.J. Broadhurst; D. Truesdell; J. Fayos; J. Clardy


Publisher
Elsevier Science
Year
1973
Tongue
French
Weight
259 KB
Volume
14
Category
Article
ISSN
0040-4039

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✦ Synopsis


Among several reasons for mechanistic interest in cycloaddition reactions of cyclooctatetraeneiron tricarbonyl (A) and related M(C0)3 complexes is the expectancy that interesting modification of reactivity in the "non-bonded" 1,3-diene moiety' might arise as a consequence