✦ LIBER ✦
Methyleniminium salts as acylating agent — one step synthesis of baccatin III from 10-deacetylbaccatin III with high selectivity
✍ Scribed by Christelle Cravallee; Eric Didier; Pascal Pecquet
- Book ID
- 104259289
- Publisher
- Elsevier Science
- Year
- 1998
- Tongue
- French
- Weight
- 260 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
New methylenimim'mrt salts were investigated as acylating agent of 10-deneetylbaecatin Ill. Thus, syntla~is of baeeatin llI was performed in one step with 79% isolated yield and 98% selectivity using the iminium salt prepared from mesyl chloride and N-ethyl~de.