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Methylene exchange reactions catalyzed by alkylidene derivatives of titanium and phosphorus

✍ Scribed by U. Klabunde; F.N. Tebbe; G.W. Parshall; R.L. Harlow


Book ID
103691513
Publisher
Elsevier Science
Year
1980
Weight
540 KB
Volume
8
Category
Article
ISSN
0304-5102

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✍ Masahiro Terada; Yukihiro Motoyama; Koichi Mikami πŸ“‚ Article πŸ“… 1994 πŸ› Elsevier Science 🌐 French βš– 273 KB

Diastereo-and enantioselective carbonyl-ene reaction of glyoxylate (2) with t&substituted olefins (3) catalyzed by chiral titanium complexes (la), derived from 6,6'-dibromo-<,l'-bi-2-naphthol and diisopropoxylitanium dihaliies. is found lo provide syn-diastereomers exclusively along with a hih Mel o