Methylation of [76]Fullerene and [84]Fullerenes; the First Oxahomo Derivatives of a Higher Fullerene.
β Scribed by Adam D. Darwish; Natalia Martsinovich; Roger Taylor
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 54 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
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The electronic structures of mono-anionized higher fullerenes (C,, C,, C, and C, ) associated with the major experimental product have been investigated bused on their optimized structures employing the semi-empirical (MIND0/3) molecular orbital calculations. Not a very drastic structural change has
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## Abstract Simple bromination of a fullerene mixture allowed the separation of C~78~ from other fullerenes in form of crystalline C~78~Br~18~. The first Xβray singleβcrystal structure of a halogenated higher fullerene, C~78~Br~18~, revealed that the addition pattern of 18 bromine atoms on the C~78