The title compound 3 was obtained during the rearrangement of isoxazol-5-yl hydrazine 1 to 1 -aminopyrazolone 2 at \(115^{\circ}\). X-ray analysis of the corresponding benzylidene derivative allowed us to achieve the structure assignment.
Methylation of 5-Amino-3-methylthio-1 H-pyrazole Derivatives and Two Related Crystal Structures
β Scribed by Xue-Ling Ren; Chao Wu; Fang-Zhong Hu; Xiao-Mao Zou; Hua-Zheng Yang
- Publisher
- John Wiley and Sons
- Year
- 2010
- Tongue
- English
- Weight
- 358 KB
- Volume
- 22
- Category
- Article
- ISSN
- 0256-7660
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## Abstract magnified image A series of ethyl 2β(1,5βdiarylβ1__H__βpyrazolβ3βyloxy)acetate derivatives (**5a**, **5b**, **5c**, **5d**, **5e**, **5f**, **5g**, **5h**, **5i**) have been efficiently synthesized by the reaction of 1,5βdiarylβ1__H__βpyrazolβ3βols (**4a**, **4b**, **4c**, **4d**, **4e