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Methylation and chlorination of internal olefins with trimethylaluminum and hydrogen chloride

โœ Scribed by Kennedy, Joseph P.; Sivaram, S.


Book ID
127024168
Publisher
American Chemical Society
Year
1973
Tongue
English
Weight
434 KB
Volume
38
Category
Article
ISSN
0022-3263

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Roth terminal and internal olefins can he efficiently converted to ketones in Dolyethylene glycol and water using palladium chloride as the catalyst. Recently, we described the application of phase transfer catalysis to the palladium catalyzed oxidation of olefins to ketones'. This is a useful react