The actions of ammonium persulfate on (feruloylated) sugar-beet pectins and ferulate have been studied by spectrophotometry, viscometry, 'H-n.m.r. spectroscopy, and gel-permeation chromatography. The reactions followed a pseudo-firstorder law with respect to pectin and ferulate, whereas the order wi
✦ LIBER ✦
Methylation analysis and mild acid hydrolysis of the “hairy” fragments of sugar-beet pectins
✍ Scribed by Fabienne Guillon; Jean-François Thibault
- Publisher
- Elsevier Science
- Year
- 1989
- Tongue
- English
- Weight
- 841 KB
- Volume
- 190
- Category
- Article
- ISSN
- 0008-6215
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✦ Synopsis
The fragments of the rhamnogalacturonan backbone carrying neutral sidechains ("hairy" fragments) of sugar-beet pectins have been subjected to methylation analysis and mild acid treatment. The fragments have similar structures which consist of a rhamnogalacturonan backbone carrying highly branched (1+5)-linked arabinans and linear (1+4)-linked galactans of low d.p. together with (1+3,6)linked galactans in low proportions. Of the feruloyl groups, 50% are esterlinked to the neutral side-chains and are removed together with arabinose or galactose residues.
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