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Methyl (Z,Z)-α-(methoxy­imino)-2-[({1-[3-(tri­fluoro­methyl)­phenyl]­ethyl­idene}amino)­oxy­methyl]­benzene­acetate

✍ Scribed by Banerjee, Kaushik ;Ligon, Axel Patrick ;Schürmann, Markus ;Preut, Hans ;Spiteller, Michael

Publisher
International Union of Crystallography
Year
2004
Tongue
English
Weight
228 KB
Volume
60
Category
Article
ISSN
1600-5368

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✦ Synopsis

Single-crystal X-ray study T = 291 K Mean '(C±C) = 0.004 A Ê Disorder in main residue R factor = 0.034 wR factor = 0.069 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

📜 SIMILAR VOLUMES

Methyl (Z,E)-α-(methoxy­imino)-2-[({1-[3
Methyl (Z,E)-α-(methoxy­imino)-2-[({1-[3-(tri­fluoro­methyl)­phenyl]­ethyl­idene}­amino)­oxy­methyl]benzene­acetate
✍ Banerjee, Kaushik ;Ligon, Axel Patrick ;Schürmann, Markus ;Preut, Hans ;Spitelle 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 196 KB

The title compound, C 20 H 19 F 3 N 2 O 4 , crystallizes with two molecules in the asymmetric unit. The important characteristics of the molecule are the two C N bonds in Z,E configuration, one in the -methoxy-system and the other in the oxymethyl side chain between the two aromatic rings.

Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-
Ethyl 2-{[(1Z)-(3-methyl-5-oxo-1-phenyl-1,5-di­hydro­pyrazol-4-yl­idene)(phenyl)­methyl]­amino}-3-phenyl­propanoate
✍ Zhang, Xin ;Zhu, Hua-Ling ;Xu, Hai-Zhen ;Dong, Mei 📂 Article 📅 2005 🏛 International Union of Crystallography 🌐 English ⚖ 189 KB

In the title compound, C 28 H 27 N 3 O 3 , the pyrazolone ring and the N atom of the 2-amino-3-phenylpropanoate group are essentially coplanar. The compound is in an enamine-keto form and its structure is stabilized by one strong intramolecular N-HÁ Á ÁO hydrogen bond.

The polyfunctionalized en­amino­ne ethyl
The polyfunctionalized en­amino­ne ethyl [(Z)-2-(2,2-di­methyl-4,6-dioxo-1,3-dioxan-5-yl­idene­methyl)-1-methyl-3-oxo-but-1-enyl­amino]­acetate
✍ Vencato, Ivo ;Cunha, Silvio ;Ferrari, Jailton ;Napolitano, Hamilton B. ;Lariucci 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 272 KB

Single-crystal X-ray study T = 293 K Mean '(C±C) = 0.003 A Ê R factor = 0.056 wR factor = 0.162 Data-to-parameter ratio = 12.9 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.