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Methyl transfer in field desorption mass spectrometry of ammonioalkanecarboxylate hydrochloride salts

✍ Scribed by Gordon W. Wood; Ronald J. Collacott


Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
353 KB
Volume
18
Category
Article
ISSN
1076-5174

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Mass spectrometry of quaternary ammonioh
✍ R. A. Sanders; A. J. DeStefano; T. Keough πŸ“‚ Article πŸ“… 1980 πŸ› John Wiley and Sons 🌐 English βš– 257 KB

Intermolecular alkyl transfer occurs during field desorption of quaternary ammoniohexanoates, resulting in mass spectra containing structurally diagnostic adduct ions. Methyl, ethyl and propyl groups attached to nitrogen readily undergo intermolecular transfer to give [M+CH,]', [M+C,H,]+ and [M+C,H,